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Deflagration

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To the SEAINT list:

Walter Sawruk introduced a term I wasn't familiar with:  deflagration.
Looked in the dictionary, wasn't there.  Searched on the internet, came
across this article by John DeHann.  I thought it was educational enough to
be passed along.

I'd like to hear your opinions on the appropriateness of posting something
like this.  My feeling is that it doesn't cost very much, and you can easily
deflagrate it if it you don't want to read it.
__________________
John P. Riley, PE, SE
Riley Engineering
20 Oakwood Drive, Blue Grass, Iowa 52726
Tel & Fax:  319-381-3949
jpriley485(--nospam--at)peoplepc.com
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Deflagrations vs. Detonations
By John D. DeHaan
California Institute of Criminalistics
Department of Justice
State of California

Deflagrations are thermal processes that proceed radially outward in all
directions through the available fuel away from the ignition source. As the
volume of the reaction zone expands with every passing moment, the larger
surface area contacts more fuel, like the surface of an inflating balloon.
The reaction starts small and gathers energy with time. This process occurs
at speeds depending largely on the chemistry of the fuel--from 1 to 10
meters per second in gasoline vapors mixed with air to hundreds of meters
per second in black powder or nitrocellulose propellants. These speeds are
less than the speed of sound in the fuel (The speed of sound through a
material is not constant, but dependent on the density of the material; the
higher its density, the higher the speed of sound will be through it).
Deflagrations, then, are thermally initiated reactions propagating at
subsonic speeds through materials like: mixtures of natural gas and air, LP
gases and air, or gasoline vapors and air; black powder or nitrocellulose
(single-base) propellants or rocket fuels. The pressures developed by
deflagrating explosions are dependent on the fuels involved, their geometry,
and the strength (failure pressure) of a confining vessel or structure (if
any). Pressures can range from 0.1psi to approximately 100psi for
gasoline:air mixtures to several thousand psi for propellants. Times of
development are on the order of thousandths of a second to a half-second or
more. Maximum temperatures are on the order of 1000-2000 degrees Celsius
(2000-4000 degrees Fahrenheit).

Detonations are very different. While a detonation is still chemically an
oxidation reaction, it does not involve a combination with oxygen. It
involves only special chemically unstable molecules that, when energized,
instantaneously splits into many small pieces that then recombine into
different chemical products releasing very large amounts of heat as they do
so. High explosives are defined as materials intended to function by
detonation, such as TNT, nitroglycerine, C4, picric acid, and dynamite. The
reaction speeds are higher than the speed of sound in the material (i.e.,
supersonic). Since most explosives are roughly the same density, a reaction
speed of 1000 m/s (3100 feet per second) is set as the minimum speed that
distinguishes detonations from deflagrations. Due to the supersonic reaction
speed, a shock wave develops in the explosive (like the sonic boom from
supersonic aircraft) that triggers the propagating reaction. Detonation
speeds are on the order of 1000-10000 m/s so times of development are on the
order of millionths of a second. Temperatures produced can be 3000-5000
degrees Celsius and pressures can be from 10000 psi to 100000 psi. It should
be noted that a few materials can transition from deflagration to detonation
depending on their geometry (long, straight galleries or pipes), starting
temperature, and manner of initiation. Double-base smokeless powders
(containing nitroglycerine), perchlorate-based flashpowders, hydrogen/air
mixtures and acetylene (pure or with air) can detonate under some
conditions.

The effects of detonations are very different from those of deflagrations.
Deflagrations tend to push, shove, and heave, often with very limited
shattering and little production of secondary missiles (fragmentation).
Building components may have time to move in response to the pressure as it
builds up and vent it. The maximum pressures developed by deflagrations are
often limited by the failure pressure of the surrounding structure.
Detonations, on the other hand, tend to shatter, pulverize and splinter
nearby materials with fragments propelled away at a very high speeds. There
is no time to move and relieve pressure so damage tends to be much more
localized (seated) in the vicinity of the explosive charge (and its
initiator) than a deflagration whose damage is more generalized. Damage from
a deflagration tends to be more severe away from the ignition point, as the
reaction energy grows with the expanding reaction (flame) front. It is for
this reason that identification of an ignition source and mechanism for a
deflagration may be more difficult than for a detonation.